- Chemical Name: METHYL PHOSPHORODICHLORIDATE
- CAS No.: 677-24-7
METHYL PHOSPHORODICHLORIDATE GMP Manufacturer Global Trade 677-24-7 with Fast Delivery
- Molecular Formula: CH3Cl2O2P
- Molecular Weight: 148.913
- Vapor Pressure: 2.21mmHg at 25°C
- Melting Point: -59 °C
- Refractive Index: n20/D 1.436(lit.)
- Boiling Point: 167.8 °C at 760 mmHg
- Flash Point: 3 °C
- PSA： 36.11000
- Density: 1.514 g/cm3
- LogP: 2.21850
METHYL PHOSPHORODICHLORIDATE(Cas 677-24-7) Usage
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Chemical Description |
Methyl phosphorodichloridate is a chemical compound with the formula CH3POCl2. |
InChI:InChI=1/CH3Cl2O2P/c1-5-6(2,3)4/h1H3
677-24-7 Relevant articles
Preparation method of bis(2,2,2-trifluoroethyl)methyl phosphate
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Paragraph 0017-0019; 0021-0023; 0025-0026; 0028-0029, (2021/01/29)
The invention discloses a synthesis meth...
The chlorination reaction of O-alkyl S-alkyl(aryl) thiophosphoric(-nic) acid derivatives with phosphorus oxychloride
He, Zheng-Jie,Chen, Wen-Bing,Ma, Fu-Peng,Zhou, Zheng-Hong,Tang, Chu-Chi
, p. 49 - 55 (2007/10/03)
It is reported that a variety of O-alkyl...
THE ISOMERIZATION/CHLORINATION OF O,O-DIALKYL PHENYLTHIOPHOSPHONATES WITH PHOSPHORUS OXYCHLORIDE - A NEW CONVENIENT SYNTHESIS OF S-ALKYL PHENYLTHIOPHOSPHONIC ACID DERIVATIVES
Tang, Chu Chi,Wu, Gui Ping,Huang, Guang Yan,Li, Zhen,Jin, Gui Yu
, p. 159 - 164 (2007/10/02)
A new method for the synthesis of S-alky...
AN IMPROVED SYNTHESIS OF MONOESTERS OF PHOSPHORIC ACID
Modro, Agnes M.,Modro, Tomasz A.
, p. 57 - 60 (2007/10/03)
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677-24-7 Process route
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67-56-1
methanol
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677-24-7
methyl dichlorophosphoridate
| Conditions | Yield |
|---|---|
|
With
trichlorophosphate;
In
diethyl ether; Petroleum ether;
1) 0 deg C, 3h; 2) 12h, 20 deg C; 3) 3h, reflux;
|
83%
|
|
With
trichlorophosphate;
In
diethyl ether;
for 2h;
|
73%
|
|
With
trichlorophosphate;
at -10 - -2 ℃;
|
70%
|
|
With
trichlorophosphate;
at 0 ℃;
for 1h;
|
47%
|
|
With
diethyl ether; trichlorophosphate;
|
|
|
With
trichlorophosphate;
at -50 ℃;
|
|
|
With
diethyl ether; phosphorus pentachloride;
at -10 ℃;
|
|
|
With
trichlorophosphate;
|
|
|
With
triethylamine; trichlorophosphate;
In
tetrahydrofuran;
Ambient temperature;
|
|
|
With
trichlorophosphate;
at 25 ℃;
Rate constant;
stop-flow system;
|
|
|
With
hydrogenchloride; lithium chloride; trichlorophosphate;
at -15 - 7 ℃;
for 2h;
under 525.053 - 600.06 Torr;
Temperature;
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99 %Chromat.
|
-
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54262-51-0
O-methyl O-phenyl S-propyl thiophosphate
-
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80553-34-0
O-Phenyl S-propyl phosphorochloridothiolate
-
-
677-24-7
methyl dichlorophosphoridate
| Conditions | Yield |
|---|---|
|
With
trichlorophosphate;
at 95 ℃;
for 5h;
|
85.5%
|
677-24-7 Upstream products
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67-56-1
methanol
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33576-92-0
O,O-dimethyl O-phenyl phosphorothioate
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5314-03-4
O,O-Dimethyl-O-(p-chlorphenyl)-thiophosphat
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6840-11-5
phenylthiophosphonic acid dimethyl ester
677-24-7 Downstream products
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409323-33-7
phosphoric acid-chloride methyl ester-p -toluidide
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146-17-8
Flavin mononucleotide
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34704-85-3
C11 H13 N2 O4 P
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33862-29-2
Methyl-N-p-Chlorphenylphosphoramidin chlorid