Home >Agrochemicals > DIMETHYL 2,6-PYRIDINEDICARBOXYLATE
- Chemical Name: DIMETHYL 2,6-PYRIDINEDICARBOXYLATE
- CAS No.: 5453-67-8
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1.What is the DIMETHYL 2,6-PYRIDINEDICARBOXYLATE ?
Dimethyl 2,6-pyridinedicarboxylate may be used in the synthesis of:ditopic macrocycle having two xylyl rings linked by diethylene glycol and 2,6-pyridinediamide spacers, which acts as host molecule capable of forming complexes with diphenylurea derivativesN,N′-bis(2-aminoethyl)dipicoloinic acid diamide Schiff base1,1′-(2,6-bispyridyl)bis-3-(9-ethylcarbazole-3-yl)-1,3-propanedione
-
-
67-56-1
methanol
-
-
499-83-2
Pyridine-2,6-dicarboxylic acid
-
-
5453-67-8
2,6-bis(methoxycarbonyl)pyridine
| Conditions | Yield |
|---|---|
|
With
thionyl chloride;
for 3h;
Heating;
|
100%
|
|
With
thionyl chloride;
for 3h;
Heating / reflux;
|
100%
|
|
With
sulfuric acid;
at 75 ℃;
for 24h;
|
100%
|
|
With
sulfuric acid;
at 75 ℃;
for 24h;
|
100%
|
|
With
sulfuric acid;
for 24h;
Reflux;
|
99%
|
|
With
thionyl chloride;
at 0 ℃;
for 5h;
Reflux;
Inert atmosphere;
|
98%
|
|
With
sulfuric acid;
for 12h;
Reflux;
|
98%
|
|
With
hydrogenchloride; 2,2-dimethoxy-propane;
for 4h;
Heating;
|
97%
|
|
With
sulfuric acid;
for 48h;
Heating;
|
96%
|
|
With
sulfuric acid;
for 18h;
Heating;
|
96%
|
|
With
sulfuric acid;
for 48h;
Reflux;
|
96%
|
|
With
sulfuric acid;
for 48h;
Reflux;
|
96%
|
|
With
sulfuric acid;
Reflux;
|
96%
|
|
With
sulfuric acid;
for 18h;
Heating;
|
96%
|
|
With
sulfuric acid;
Heating;
|
95%
|
|
With
sulfuric acid;
for 6h;
Reflux;
|
95%
|
|
With
thionyl chloride;
for 3h;
Schlenk technique;
Inert atmosphere;
Reflux;
|
95%
|
|
With
sulfuric acid;
for 12h;
Reflux;
|
95%
|
|
With
sulfuric acid;
at 70 ℃;
for 24h;
|
95%
|
|
With
sulfuric acid;
for 3h;
Reflux;
|
94%
|
|
With
sulfuric acid;
Reflux;
|
94%
|
|
With
sulfuric acid;
Reflux;
|
92%
|
|
With
sulfuric acid;
for 9h;
Inert atmosphere;
Reflux;
|
91%
|
|
With
sulfuric acid;
for 3h;
Reflux;
|
91%
|
|
With
sulfuric acid;
at 30 - 70 ℃;
|
91%
|
|
With
thionyl chloride;
for 18h;
Reagent/catalyst;
Inert atmosphere;
Reflux;
|
91.4%
|
|
With
sulfuric acid;
for 3h;
Reflux;
|
91.5%
|
|
With
sulfuric acid;
In
methanol;
at 20 ℃;
for 3h;
Reflux;
|
91%
|
|
With
sulfuric acid;
for 16h;
Reflux;
|
90%
|
|
With
thionyl chloride;
at 0 ℃;
for 14h;
Cooling with ice;
Reflux;
|
88%
|
|
With
sulfuric acid;
for 4h;
Reflux;
|
87%
|
|
With
acetyl chloride;
at 30 - 90 ℃;
for 20h;
|
86%
|
|
With
acetyl chloride;
|
86%
|
|
With
sulfuric acid;
for 100h;
Heating;
|
85%
|
|
With
sulfuric acid;
for 20h;
Reflux;
|
85%
|
|
With
sulfuric acid;
Reflux;
|
85%
|
|
Pyridine-2,6-dicarboxylic acid;
With
thionyl chloride;
for 72h;
Reflux;
methanol;
for 3h;
Reflux;
|
85%
|
|
Pyridine-2,6-dicarboxylic acid;
With
thionyl chloride;
In
N,N-dimethyl-formamide;
for 10h;
Inert atmosphere;
Schlenk technique;
Reflux;
methanol;
In
N,N-dimethyl-formamide;
for 1h;
Inert atmosphere;
Schlenk technique;
Reflux;
|
85.1%
|
|
With
sulfuric acid;
at 80 ℃;
for 3h;
|
85.2%
|
|
With
sulfuric acid;
at 70 ℃;
for 48h;
|
83%
|
|
With
sulfuric acid;
at 67 ℃;
for 13h;
|
83%
|
|
With
thionyl chloride;
at 0 - 65 ℃;
|
82%
|
|
With
sulfuric acid;
Reflux;
|
82%
|
|
With
sulfuric acid;
at 70 ℃;
|
81%
|
|
With
sulfuric acid;
at 70 ℃;
|
81%
|
|
With
thionyl chloride;
at 0 ℃;
Inert atmosphere;
Reflux;
|
80%
|
|
With
sulfuric acid;
for 48h;
Inert atmosphere;
Reflux;
|
80%
|
|
With
sulfuric acid;
for 24h;
Heating;
|
79%
|
|
With
sulfuric acid;
at 70 ℃;
for 48h;
|
78%
|
|
for 24h;
Reflux;
|
78%
|
|
With
sulfuric acid;
at 85 ℃;
for 24h;
|
77%
|
|
With
sulfuric acid;
at 20 - 90 ℃;
|
76%
|
|
With
hydrogenchloride; 2,2-dimethoxy-propane;
|
75%
|
|
With
sulfuric acid;
for 18h;
Reflux;
|
75%
|
|
With
hydrogenchloride; 2,2-dimethoxy-propane;
In
water;
at 100 ℃;
for 4h;
|
73%
|
|
With
sulfuric acid;
for 4h;
Reflux;
|
73%
|
|
With
sulfuric acid;
Heating;
|
73%
|
|
With
sulfuric acid;
for 48h;
Reflux;
|
70%
|
|
With
sulfuric acid;
for 48h;
Reflux;
|
68%
|
|
With
sulfuric acid;
for 48h;
Reflux;
|
66%
|
|
With
sulfuric acid;
for 24h;
Reflux;
|
30%
|
|
|
|
|
With
sulfuric acid;
Heating;
|
82.27 g
|
|
With
acetyl chloride;
|
|
|
With
sulfuric acid;
|
|
|
With
hydrogen cation;
|
|
|
With
sulfuric acid;
Heating;
|
|
|
With
thionyl chloride;
|
|
|
With
sulfuric acid;
|
|
|
With
acetyl chloride;
|
|
|
methanesulfonic acid;
at 240 ℃;
under 26252.6 Torr;
Industry scale;
Microwave irradiation;
|
|
|
With
sulfuric acid;
Heating;
|
|
|
With
acetyl chloride;
at 20 ℃;
for 24h;
|
|
|
With
acetyl chloride;
|
|
|
With
thionyl chloride;
at 20 ℃;
for 24h;
|
|
|
With
acetyl chloride;
|
|
|
With
sulfuric acid;
for 48h;
Reflux;
|
|
|
With
thionyl chloride;
at 0 ℃;
for 20h;
Reflux;
|
|
|
With
thionyl chloride;
for 6h;
Reflux;
|
|
|
With
sulfuric acid;
Reflux;
|
|
|
With
sulfuric acid;
|
|
|
With
sulfuric acid;
|
|
|
With
sulfuric acid;
|
|
|
With
sulfuric acid;
|
|
|
With
thionyl chloride;
for 4h;
Reflux;
|
-
-
499-83-2
Pyridine-2,6-dicarboxylic acid
-
-
5453-67-8
2,6-bis(methoxycarbonyl)pyridine
| Conditions | Yield |
|---|---|
|
With
methanol; thionyl chloride;
for 16h;
Reflux;
|
93%
|
|
With
hydrogenchloride;
|
|
|
Multi-step reaction
with
2
steps
1: thionyl chloride / Heating
2: Heating
With
thionyl chloride;
|
|
|
Multi-step reaction
with
4
steps
1: thionyl chloride / Heating
2: Heating
3: 1.) Et4
NBF4
/ 1.) electrolysis, acetonitrile, 2.) acetonitrile, 24 h
4: Et4
NBF4
/ 1.) electrolysis, acetonitrile, 2.) acetonitrile, 24 h
With
thionyl chloride; N,N,N,N-tetraethylammonium tetrafluoroborate;
|
|
|
Multi-step reaction
with
2
steps
1: THF / 24 h / Heating
2: 1 h / 0 °C
With
tetrahydrofuran;
|
|
|
Multi-step reaction
with
2
steps
1: phosphorus pentachloride
With
phosphorus pentachloride;
|
|
|
Multi-step reaction
with
2
steps
1: thionyl chloride / 3 h / Reflux
2: N-ethyl-N,N-diisopropylamine / tetrahydrofuran / 4 h / Reflux
With
thionyl chloride; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran;
|
|
|
Multi-step reaction
with
2
steps
1: thionyl chloride / 0.75 h / Cooling with ice; Reflux
2: 0.5 h / 0 °C / Reflux
With
thionyl chloride;
|
|
|
Multi-step reaction
with
2
steps
1: thionyl chloride / 12 h / 75 °C
2: 0.5 h / 65 °C
With
thionyl chloride;
|
|
|
Multi-step reaction
with
2
steps
1: thionyl chloride / 4 h / Reflux; Inert atmosphere; Schlenk technique
2: dichloromethane / 2 h / 20 °C / Inert atmosphere; Schlenk technique
With
thionyl chloride;
In
dichloromethane;
|
|
|
Multi-step reaction
with
2
steps
1: thionyl chloride / 6 h / 0 °C / Reflux; Inert atmosphere
2: 12 h / 0 °C / Reflux; Inert atmosphere
With
thionyl chloride;
|
|
|
With
thionyl chloride;
In
methanol;
at 0 - 80 ℃;
for 6h;
Inert atmosphere;
|
2.What is the CAS number for DIMETHYL 2,6-PYRIDINEDICARBOXYLATE ?
The CAS number of DIMETHYL 2,6-PYRIDINEDICARBOXYLATE is 5453-67-8.
More information of DIMETHYL 2,6-PYRIDINEDICARBOXYLATE 5453-67-8 are:
|
CAS?Number |
5453-67-8 |
|
Density |
1.231 g/cm3 |
|
Melting Point |
121-125 °C(lit.) |
|
Boiling Point |
321.7 °C at 760 mmHg |
|
Flash Point |
148.3 °C |
|
Vapor Pressure |
0.000293mmHg at 25°C |
|
Refractive Index |
1.516 |
|
HS CODE |
29333990 |
|
PSA |
65.49000 |
|
LogP |
0.65480 |
|
Pka |
-0.46±0.10(Predicted) |
3.What are another words for DIMETHYL 2,6-PYRIDINEDICARBOXYLATE ?
Synonyms?for?DIMETHYL 2,6-PYRIDINEDICARBOXYLATE 5453-67-8:2,6-Pyridinedicarboxylicacid, dimethyl ester (6CI,7CI,8CI,9CI);2,6-Bismethoxycarbonylpyridine;2,6-Dicarbomethoxypyridine;2,6-Dipicolinic acid dimethyl ester;Dimethyl2,6-pyridinedicarboxylate;Dipicolinic acid dimethyl ester;NSC 18855;
4.What is the molecular formula of DIMETHYL 2,6-PYRIDINEDICARBOXYLATE?
The chemical formula of ?DIMETHYL 2,6-PYRIDINEDICARBOXYLATE is?C9H9NO4 which containing 9 Carbon atoms,9 Hydrogen atoms,1 Nitrogen atoms and 4 Oxygen atoms,and the molecular weight of??DIMETHYL 2,6-PYRIDINEDICARBOXYLATE?is 195.175.
5.What is DIMETHYL 2,6-PYRIDINEDICARBOXYLATE (5453-67-8) used for?
DIMETHYL 2,6-PYRIDINEDICARBOXYLATE, also known as dimethylpyridine-2,6-dicarboxylate, is an off-white solid with a calculated standard molar enthalpy of formation derived from the standard molar enthalpy of combustion. It is a chemical compound that serves as a key intermediate in the synthesis of various organic compounds.
InChI:InChI=1/C9H9NO4/c1-13-8(11)6-4-3-5-7(10-6)9(12)14-2/h3-5H,1-2H3
Relevant articles related to DIMETHYL 2,6-PYRIDINEDICARBOXYLATE:
|
Article |
Source |
|
Structural, spectroscopic and thermal characterization of 2-tert-butylaminomethylpyridine-6-carboxylic acid methylester and its Fe(III), Co(II), Ni(II), Cu(II), Zn(II) and UO2(II) complexes |
Mohamed, Gehad G.,El-Gamel, Nadia E.A. , p. 1089 - 1096 (2005) |
|
NMR and TRLFS studies of Ln(III) and An(III) C5-BPP complexes |
Adam, Christian,Beele, Bj?rn B.,Geist, Andreas,Müllich, Udo,Kaden, Peter,Panak, Petra J. , p. 1548 - 1561 (2015) |
6.Buy DIMETHYL 2,6-PYRIDINEDICARBOXYLATE with the best price .
Hubei Sacly chemicals Technology Co.,Ltd is a quality supplier of DIMETHYL 2,6-PYRIDINEDICARBOXYLATE. Our main goal is customer satisfaction. Contact us to negotiate the best price for your business on DIMETHYL 2,6-PYRIDINEDICARBOXYLATE 5453-67-8.